US EPA

6907237 

Journal Article 

THE RAMAN STUDY OF AMPHIBOLES 

Apopei, AI; Buzgar, N 

2010 

56 

1 

57-83 

English 

Raman spectroscopy is a simple, powerful and fast method to identify and distinguish between different minerals from the amphibole group of the inosilicate class. We analyzed samples of grunerite, actinolite, nephrite, Cr - actinolite (smaragdite), uralite (var. of actinolite), tremolite, pargasite, glaucophane and riebeckite in order to determine their Raman spectra and their fingerprint. The structure of these amphiboles belongs to the space group C2/m. Also, through this work we intend to show types of linkages between Si and bridging O (O^sub b^) or non-bridging O (O^sub nb^), and complex vibrations that occur in all amphibole spectra, corresponding to the symmetric stretching modes (ν^sub s^) of the Si-O^sub b^-Si bridges or O-Si-O linkages and to the asymmetric stretching modes (ν^sub as^) of the Si-O^sub b^-Si bridges and O-Si-O linkages. The most distinct Raman peak detected in this Raman study of amphiboles is around 660-675 cm^sup -1^, which is assigned to the ν^sub 1^/ν^sub s^ (symmetric stretching vibrations) of the Si-O^sub b^-Si bridges. Some spectra present two very weak peaks at ~2330 cm^sup -1^ and ~2437 cm^sup -1^, respectively, due to the substitution of K or Na with H^sub 3^O^sup +^ (K, Na [Lef-right arrow] H^sub 3^O^sup +^) and NH^sub 4^^sup +^ (K, Na [Lef-right arrow] NH^sub 4^^sup +^); these spectral bands were identified at potassium micas. [PUBLICATION ABSTRACT] 

Earth Sciences--Geology; Minerals; Spectrum analysis