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Citation
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HERO ID
6907817
Reference Type
Journal Article
Title
N,N '-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diamine
Author(s)
Prasath, R; Bhavana, P; Ng, SW; Tiekink, ERT; ,
Year
2010
Is Peer Reviewed?
Yes
Journal
Acta Crystallographica. Section E: Structure Reports Online
ISSN:
1600-5368
Publisher
WILEY-BLACKWELL
Location
MALDEN
Page Numbers
O3123-U201
PMID
21589427
DOI
10.1107/S160053681004540X
Web of Science Id
WOS:000285090900012
Abstract
The complete molecule of the title compound, C24H20Cl2N4, is generated by a crystallographic inversion centre. A kink in the molecule is evident [C-N-C-C torsion angle = -147.0 (3)degrees] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) angstrom] and quinoline residues [N-C-C-C = -12.4 (4)degrees]. In the crystal, a combination of pi-pi [pyridine-benzene centroid-centroid distance = 3.5670 (14) angstrom] and C-H center dot center dot center dot N contacts leads to supramolecular chains propagating in [010].
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