Hexasilylated total carbomer of benzene | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6922263

Reference Type

Journal Article

Title

Hexasilylated total carbomer of benzene

Author(s)

Zou, C; Duhayon, C; Maraval, V; Chauvin, R; ,

Year

2007

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

4337-4341

Language

English

PMID

17471483

DOI

10.1002/anie.200605262

Web of Science Id

WOS:000247130400022

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34447256320&doi=10.1002%2fanie.200605262&partnerID=40&md5=86b8099cde0a1723f22bb11795124ce8
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Abstract

(Chemical Equation Presented) A close cousin of benzene: The cobalt-assisted reductive aromatization of a hexaalkynyl [6]pericyclyne afforded a fully expanded carbobenzene derivative (see scheme) as the first carbomer without stabilizing aromatic substituents. The triethylsilyl groups ensured high solubility and allowed full spectroscopic characterization of the aromatic macrocycle. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.