Tale of two isomers: A stable phenyl hydride and a high-spin (S=3) benzene complex of chromium | Health & Environmental Research Online (HERO)

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HERO ID

6922509

Reference Type

Journal Article

Title

Tale of two isomers: A stable phenyl hydride and a high-spin (S=3) benzene complex of chromium

Author(s)

Monillas, WH; Yap, GPA; Theopold, KH; ,

Year

2007

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

6692-6694

Language

English

PMID

17668893

DOI

10.1002/anie.200701933

Web of Science Id

WOS:000249438900023

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34548634352&doi=10.1002%2fanie.200701933&partnerID=40&md5=23f805d76759364b2cfc5c24314eff52
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Abstract

(Chemical Equation Presented) Staying put: A binuclear phenyl hydride complex of chromium resists benzene formation by reductive elimination, even though the isomeric μ,-η6:η6 benzene complex can be prepared independently (see scheme, Ar = 2,6-iPr2(C 6H3)). Whereas the phenyl hydride shows evidence for metal-metal bonding and antiferromagnetic coupling, the bridging benzene complex features extremely strong ferromagnetic coupling with an S = 3 ground state. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.