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HERO ID
6922658
Reference Type
Journal Article
Title
Hydrogenation of arenes by dual activation: reduction of substrates ranging from benzene to C60 fullerene under ambient conditions
Author(s)
Deshmukh, RR; Lee, JW; Shin, US; Lee, JY; Song, CE; ,
Year
2008
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Publisher
WILEY-V C H VERLAG GMBH
Location
WEINHEIM
Volume
47
Issue
45
Page Numbers
8615-8617
Language
English
PMID
18846536
DOI
10.1002/anie.200803850
Web of Science Id
WOS:000260727400013
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-55249084927&doi=10.1002%2fanie.200803850&partnerID=40&md5=460cd340f73174db0543bda520bb8097
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Abstract
(Chemical Equation Presented) Tackling aromaticity: The title reaction was accomplished by simultaneous activation of molecular hydrogen and the aromatic substrate by Pd/C and a Lewis acidic ionic liquid, respectively. Even benzene and C60 fullerene were hydrogenated under ambient conditions (1 bar of H2 at room temperature). An ionic hydrogenation mechanism (see scheme) is supported by characterization of a stabilized arenium intermediate. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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