Hydrogenation of arenes by dual activation: reduction of substrates ranging from benzene to C60 fullerene under ambient conditions | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

6922658

Reference Type

Journal Article

Title

Hydrogenation of arenes by dual activation: reduction of substrates ranging from benzene to C60 fullerene under ambient conditions

Author(s)

Deshmukh, RR; Lee, JW; Shin, US; Lee, JY; Song, CE; ,

Year

2008

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

8615-8617

Language

English

PMID

18846536

DOI

10.1002/anie.200803850

Web of Science Id

WOS:000260727400013

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-55249084927&doi=10.1002%2fanie.200803850&partnerID=40&md5=460cd340f73174db0543bda520bb8097
Exit

Abstract

(Chemical Equation Presented) Tackling aromaticity: The title reaction was accomplished by simultaneous activation of molecular hydrogen and the aromatic substrate by Pd/C and a Lewis acidic ionic liquid, respectively. Even benzene and C60 fullerene were hydrogenated under ambient conditions (1 bar of H2 at room temperature). An ionic hydrogenation mechanism (see scheme) is supported by characterization of a stabilized arenium intermediate. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.