Selective Reduction of Carboxylic Acids to Aldehydes by a Ruthenium-catalyzed Reaction with 1,2-Bis(dimethylsilyl)benzene | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6924455

Reference Type

Journal Article

Title

Selective Reduction of Carboxylic Acids to Aldehydes by a Ruthenium-catalyzed Reaction with 1,2-Bis(dimethylsilyl)benzene

Author(s)

Miyamoto, K; Motoyama, Y; Nagashima, H; ,

Year

2012

Is Peer Reviewed?

Yes

Journal

Chemistry Letters
ISSN: 0366-7022
EISSN: 1348-0715

Publisher

CHEMICAL SOC JAPAN

Location

TOKYO

Volume

Issue

Page Numbers

229-231

Language

English

DOI

10.1246/cl.2012.229

Web of Science Id

WOS:000303273800009

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84857283138&doi=10.1246%2fcl.2012.229&partnerID=40&md5=12110112598a9d7f333f40d4ecf7c0a3
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Abstract

Novel transformation of carboxylic acids to aldehydes is achieved by a one-pot procedure consisting of a ruthenium-catalyzed hydrosilane reduction with 1,2-bis(dimethylsilyl)benzene (2) followed by hydrolysis of the resulting cyclic disilylacetals 4.