Tuning the structural topologies of two luminescent metal-organic frameworks through altering auxiliary ligand | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6926676

Reference Type

Journal Article

Title

Tuning the structural topologies of two luminescent metal-organic frameworks through altering auxiliary ligand

Author(s)

Yang, Guibin; Sun, ZHai; ,

Year

2013

Is Peer Reviewed?

Yes

Journal

Inorganic Chemistry Communications
ISSN: 1387-7003

Publisher

ELSEVIER SCIENCE BV

Location

AMSTERDAM

Page Numbers

94-96

DOI

10.1016/j.inoche.2012.12.022

Web of Science Id

WOS:000316532300023

Abstract

Two new metal-organic frameworks, [Zn-2(FA)(2)(bix)(2)](n) center dot 3nH(2)O (1) and [Zn(FA)(bib)](n) (2), (H(2)FA = fumaric acid, bix = 4,4'-bis(imidazol-1-ylmethyl)benzene, bib = 1,4-bis(imidazolyl)butane), have been synthesized by combining the fumaric acid and flexible imidazole-based ligands with Zn(II) salts under hydrothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 is a 4-fold interpenetrated unc topological net, and 2 is a 5-fold interpenetrated dia topological net. Moreover, the luminescent properties of the two compounds were also investigated in the solid state at room temperature. Crown Copyright (c) 2013 Published by Elsevier B.V. All rights reserved.