Aggregation Behavior of Sodium Dodecylbenzene Sulfonate with Ca2+ by Resonance Light Scattering Method | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

6926784

Reference Type

Journal Article

Title

Aggregation Behavior of Sodium Dodecylbenzene Sulfonate with Ca2+ by Resonance Light Scattering Method

Author(s)

Li Zhen-Quan; Song Xin-Wang; Yan Lan; Tian Zhi-Ming; Liu Xiao-Yu; Zhou Hai-Ping; Wu Xia; ,

Year

2009

Is Peer Reviewed?

Yes

Journal

Chinese Journal of Analytical Chemistry / Fen Xi Hua Xue
ISSN: 0253-3820

Publisher

ELSEVIER SCIENCE INC

Location

NEW YORK

Page Numbers

1061-1064

Web of Science Id

WOS:000268522400026

Abstract

A resonance light scattering (RLS) method for the determination of critical micelle concentration (CMC) of sodium dodecyl benzene sulfonate (SDBS) was proposed. Under room temperature, the RLS intensity of the SDBS system increased with increasing SDBS concentration. And when the concentration of SDBS approached CMC, the RLS intensity had increased sharply. The RLS peaks were appeared at 330 nm and 396 nut, respectively. The plot of the RLS intensity at 396 nm versus SDBS concentration was S-Curve. The concentration of SDBS at the intersection point of two tangents to S-curve was considered as SBDS CMC. This result was consistent with the results of the pyrene probe fluorescence spectrometry and electrical conductivity method. The influences of the concentration of Ca2+ on the aggregation behave of SDBS and SDBS-emulsion OP(OP) systems were studied by the RLS method. The results indicated that the mixed system of SDBS-OP (1:3) had better anti-calcium properties.