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HERO ID
6930576
Reference Type
Journal Article
Title
Sodium N-bromo-2-chloro-benzene-sulfonamidate sesquihydrate
Author(s)
Gowda, BT; Foro, S; Shakuntala, K; ,
Year
2011
Is Peer Reviewed?
Yes
Journal
Acta Crystallographica. Section E: Structure Reports Online
ISSN:
1600-5368
Language
English
PMID
21836866
DOI
10.1107/S160053681102071X
Abstract
In the title compound, Na(+)·C(6)H(4)BrClNO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The Na(+) cation shows a pseudo-octa-hedral coordination provided by three O atoms of water mol-ecules and three sulfonyl O atoms of different N-bromo-2-chloro-benzene-sulfonamidate anions. The S-N distance of 1.579 (6) Å is consistent with an S=N double-bond character. The crystal structure is stabilized by O-H⋯Br, O-H⋯N and O-H⋯O hydrogen bonds.
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