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6932826 
Journal Article 
28-Hetero-2,7-Naphthiporphyrins: Horizontal Expansion of the m-Benziporphyrin Macrocycle 
Szyszko, B; Matviyishyn, M; Hirka, S; Pacholska-Dudziak, Ewa; Bialonska, A; Latos-Grazynski, L; , 
2019 
1 
Organic Letters
ISSN: 1523-7060
EISSN: 1523-7052 
AMER CHEMICAL SOC 
WASHINGTON 
7009-7014 
31423794 
WOS:000485089300085 
Replacement of the m-phenylene moiety of m-benziporphyrins with the 2,7-naphthalenyl subunit yielded 28-hetero-2,7-naphthiporphyrins-macrocycles that can be considered as expanded carbaporphyrinoids. This group retains some features of parent m-benziporphyrins, but due to larger size and different shape of the macrocyclic cavity, their coordination properties are different. Upon reduction and conformational rearrangement the 28-thia- and 28-selena-2,7-naphthiporphyrin form organophosphorus(V) complexes.