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HERO ID
6935154
Reference Type
Journal Article
Title
[Cu(4-phenylpyridine)(4)(trifluoromethanesulfonate)(2)], a Werner complex that exhibits high selectivity for o-xylene
Author(s)
Kaluza, AM; Mukherjee, S; Wang, ShiQ; O'Hearn, DJ; Zaworotko, MJ; ,
Year
2020
Is Peer Reviewed?
Yes
Journal
Chemical Communications
ISSN:
1359-7345
EISSN:
1364-548X
Publisher
ROYAL SOC CHEMISTRY
Location
CAMBRIDGE
Page Numbers
1940-1943
PMID
31950945
DOI
10.1039/c9cc09525j
Web of Science Id
WOS:000514651200031
Abstract
[Cu(4-phenylpyridine)(4)(trifluoromethanesulfonate)(2)] is a new Werner complex that exhibits switching behaviour between non-porous (apohost) and porous (guest-loaded) phases upon exposure to o-xylene but not when exposed to other C8 isomers. High o-xylene selectivity (>6) vs. the other C8 isomers was observed from binary mixtures, only the third occurrence across all sorbent types.
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