Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

6944564

Reference Type

Journal Article

Title

Insight into anion effects on catechol oxidation catalysis: cyclodimeric Cu(II) complexes containing 1,3,5-tris(nicotinoyloxy-methyl)benzene

Author(s)

Kim, D; Lee, S; Lee, YA; Jung, OkS; ,

Year

2020

Is Peer Reviewed?

Journal

Transition Metal Chemistry
ISSN: 0340-4285

Publisher

SPRINGER

Location

DORDRECHT

Page Numbers

65-70

DOI

10.1007/s11243-019-00358-8

Web of Science Id

WOS:000492639800001

Abstract

Self-assembly of CuX2 with C-3-symmetric tridentate ligand, 1,3,5-tris(nicotinoyloxy-methyl)benzene (L), affords thermodynamically stable C-2-symmetric metallacyclodimers, [Cu2X2L2(H2O)(2)]X-2(H2O)(2) (X- = NO3-, BF4-, and ClO4-) in high yields. These cyclodimeric species show the significant anion effects on the catechol oxidation catalysis in chloroform in the order [Cu-2(NO3)(2)L-2(H2O)(2)](NO3)(2)(H2O)(2) > [Cu-2(BF4)(2)L-2(H2O)(2)](BF4)(2)(H2O)(2) > [Cu-2(ClO4)(2)L-2(H2O)(2)](ClO4)(2)(H2O)(2).