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6949923 
Journal Article 
Tripodal tris-disulfides as capping agents for a controlled mixed functionalization of gold nanoparticles 
De Luca, G; Minuti, L; Temperini, A; Barattucci, A; Plutino, MR; Bonaccorsi, P; Trovato, V; Mancuso, A; Papalia, T; Pistone, A; Casaletto, MPia; Mezzi, A; Brunetti, B; , 
2018 
New Journal of Chemistry
ISSN: 1144-0546
EISSN: 1369-9261 
ROYAL SOC CHEMISTRY 
CAMBRIDGE 
16436-16440 
The design and synthesis of tripodal 1,3,5-R-2,4,6-R-benzene tris-disulfides (R = Et, R = phenyl or alkyl) is reported. These multi-armed systems were employed in the stable capping of colloidal AuNPs, allowing control of the ratio between the benzene core and peripheral moieties. These systems were shown to act as sensing nanomaterials for nitro aromatic explosives.