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Citation
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HERO ID
6965615
Reference Type
Journal Article
Title
New, stable and reusable magnetic Fe3O4/PEG@CPTMS-thioaminophenol@Ni nanocatalyst for the synthesis of dispiro-cyclopropanes's Meldrum's acid
Author(s)
Pesyan, NN; Bibak, S; Aalinejad, M; ,
Year
2020
Is Peer Reviewed?
Yes
Journal
Journal of the Iranian Chemical Society
ISSN:
1735-207X
EISSN:
1735-2428
Publisher
SPRINGER
Location
NEW YORK
Page Numbers
411-422
DOI
10.1007/s13738-019-01775-3
Web of Science Id
WOS:000513235100013
Abstract
Magnetic Fe3O4/PEG@CPTMS-thioaminophenol@Ni nanocatalyst as a heterogeneous, stable and reusable nanocatalyst was formed. This nanocatalyst was characterized by FT-IR, XRD, TGA, ICP, SEM, EDS and VSM techniques and was used for six times without decreasing activity. This nanocatalyst was used successfully for the synthesis of 3,3,10,10-tetramethyl-13-aryl(alkyl)-2,4,9,11-tetraoxadispiro[5.0.5(7).1(6)]tridecane-1,5,8,12-tetraones (dispiro-cyclopropane's based on Meldrum's acid) by the reaction of various aldehydes and Meldrum's acid in the presence of triethylamine and cyanogen bromide in excellent yield. Graphic abstract
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