Synthesis and Crystal Structure of 6-Ethoxy-4 ',6 '-dibromo-2,2 '-[ethylenedioxybis(nitrilomethylidyne)]diphenol | Health & Environmental Research Online (HERO)

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HERO ID

6975808

Reference Type

Journal Article

Title

Synthesis and Crystal Structure of 6-Ethoxy-4 ',6 '-dibromo-2,2 '-[ethylenedioxybis(nitrilomethylidyne)]diphenol

Author(s)

Liu, X; Wu, J; Zhang, Y; Li, G; Wang, Li; Dong, X; ,

Year

2013

Is Peer Reviewed?

Yes

Journal

Asian Journal of Chemistry
ISSN: 0970-7077
EISSN: 0975-427X

Publisher

ASIAN JOURNAL OF CHEMISTRY

Location

SAHIBABAD

Volume

Issue

Page Numbers

5039-5041

Language

English

DOI

10.14233/ajchem.2013.14363

Web of Science Id

WOS:000325087800078

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84878135983&doi=10.14233%2fajchem.2013.14363&partnerID=40&md5=3ea27c1baf70759909e4346635a55c4f
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Abstract

The title compound, 6-ethoxy-4',6'-dibromo-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol with the molecular formula C18H18Br2N2O5, adopts an L-shaped configuration, in which the benzene units are approximately perpendicular, making a dihedral angle of 76.39(3)degrees. Intramolecular H-bonds are formed between the OH groups and the N atoms. In the crystal structure, each molecule links other molecules into an infinite three-dimensional supramolecular structure by intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi hydrogen bond interactions.