US EPA

7010113 

Journal Article 

Mobility and redox transformation of arsenic during treatment of artificially recharged groundwater for drinking water production 

Ahmad, A; Heijnen, Leo; de Waal, L; Battaglia-Brunet, F; Oorthuizen, Wim; Pieterse, B; Bhattacharya, P; van Der Wal, A; , 

2020 

1 

Water Research
ISSN: 0043-1354
EISSN: 1879-2448 

PERGAMON-ELSEVIER SCIENCE LTD 

OXFORD 

178 

115826 

English 

32361349 

10.1016/j.watres.2020.115826 

WOS:000534606400019 

https://linkinghub.elsevier.com/retrieve/pii/S0043135420303638
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In this study we investigate opportunities for reducing arsenic (As) to low levels, below 1 mu g/L in produced drinking water from artificially infiltrated groundwater. We observe that rapid sand filtration is the most important treatment step for the oxidation and removal of As at water treatment plants which use artificially recharged groundwater as source. Removal of As is mainly due to As co-precipitation with Fe(III)(oxyhydr)oxides, which shows higher efficiency in rapid sand filter beds compared to aeration and supernatant storage. This is due to an accelerated oxidation of As(III) to As(V) in the filter bed which may be caused by the manganese oxides and/or As(III) oxidizing bacteria, as both are found in the coating of rapid sand filter media grains by chemical analysis and taxonomic profiling of the bacterial communities. Arsenic removal does not take place in treatment steps such as granular activated carbon filtration, ultrafiltration or slow sand filtration, due to a lack of hydrolyzing iron in their influent and a lack of adsorption affinity between As and the filtration surfaces. Further, we found that As reduction to below 1 mu g/L can be effectively achieved at water treatment plants either by treating the influent of rapid sand filters by dosing potassium permanganate in combination with ferric chloride or by treating the effluent of rapid sand filters with ferric chloride dosing only. Finally, we observe that reducing the pH is an effective measure for increasing As co-precipitation with Fe(III)(oxyhydr)oxides, but only when the oxidized arsenic, As(V), is the predominant species in water. (C) 2020 The Author(s). Published by Elsevier Ltd.