Health & Environmental Research Online (HERO)


Print Feedback Export to File
7120298 
Journal Article 
Encapsulated green magnetic nanoparticles for the removal of toxic Pb2+ and Cd2+ from water: Development, characterization and application 
Ali, I; Peng, C; Lin, D; Saroj, DP; Naz, I; Khan, ZM; Sultan, M; Ali, M; , 
2019 
Yes 
Journal of Environmental Management
ISSN: 0301-4797
EISSN: 1095-8630 
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD 
LONDON 
234 
273-289 
English 
30634120 
WOS:000460195000030 
Current research is based on an innovative approach of the fabrication of encapsulated sustainable, green, phytogenic magnetic nanoparticles (PMNPs), to inhibit the generation of secondary pollutants (Iron/Fe degrees) during water treatment applications. These novel bio-magnetic membrane capsules (BMMCs) were prepared using twostep titration gel crosslink method, with polyvinyl alcohol and sodium alginate matrix as the model encapsulating materials to eliminate potentially toxic metals (Pb2+ and Cd2+) from water. The development of BMMCs was characterized by FTIR, XRD, XPS, SEM, VSM, TGA and EDX techniques. The effects of various operating parameters, adsorbent dose, contact time, solution pH, temperature, initial concentration of metals cations and co-existing ions were studied. The hysteresis loops have illustrated an excellent super-paramagnetic nature, demonstrating the smooth encapsulation of PMNPs without losing their magnetic properties. The maximum monolayer adsorptive capacities estimated at pH 6.5 by the Langmuir isotherm model were 548 and 610.67 mg/g for Pb2+ and Cd2+, respectively. The novel BMMCs did not only control oxidation of PMNPs but also sustained the adsorptive removal over a wide range of pH (3-8), and the electrostatic interaction and ion-exchange were the core adsorption mechanisms. The BMMCs could easily be regenerated using 25% HNO3 as an eluent for successful usage in seven repeated cycles. Therefore, the BMMCs as a material can be used as an excellent sorbent or composite material to remove toxic metals Pb2+ and Cd2+, showing strong potential for improving water and wastewater treatment technologies.