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7205778 
Journal Article 
Recycling Perovskite Solar Cells To Avoid Lead Waste 
Binek, A; Petrus, ML; Huber, N; Bristow, H; Hu, Y; Bein, T; Docampo, P; , 
2016 
1 
ACS Applied Materials & Interfaces
ISSN: 1944-8244
EISSN: 1944-8252 
AMER CHEMICAL SOC 
WASHINGTON 
12881-12886 
27149009 
WOS:000376825800039 
Methylammonium lead iodide (MAPbI3) perovskite based solar cells have recently emerged as a serious competitor for large scale and low-cost photovoltaic technologies. However, since these solar cells contain toxic lead, a sustainable procedure for handling the cells after their operational lifetime is required to prevent exposure of the environment to lead and to comply with international electronic waste disposal regulations. Herein, we report a procedure to remove every layer of the solar cells separately, which gives the possibility to selectively isolate the different materials. Besides isolating the toxic lead iodide in high yield, we show that the PbI, can be reused for the preparation of new solar cells with comparable performance and in this way avoid lead waste. Furthermore, we show that the most expensive part of the solar cell, the conductive glass (FTO), can be reused several times without any reduction in the performance of the devices. With our simple recycling procedure, we address both the risk of contamination and the waste disposal of perovskite based solar cells while further reducing the cost of the system. This brings perovskite solar cells one step closer to their introduction into commercial systems.