Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
7254696
Reference Type
Journal Article
Title
Highly efficient tetrafluoroethylene recovery for batch polymerization system: Membrane preparation and process development
Author(s)
Wang, H; Dai, Yan; Ruan, X; Jiang, X; Yan, X; Xiao, Wu; He, G; ,
Year
2018
Is Peer Reviewed?
Yes
Journal
Journal of Membrane Science
ISSN:
0376-7388
Publisher
ELSEVIER SCIENCE BV
Location
AMSTERDAM
Page Numbers
403-410
DOI
10.1016/j.memsci.2017.12.035
Web of Science Id
WOS:000424393100043
Abstract
In tetrafluoroethylene (TFE) batch polymerization, H-2 is utilized to stabilize pressure and control reaction degree. TFE lost in the purge can account for about 6.0% of the loaded monomer. In this work, membrane-based separation system was presented to effectually reduce TFE loss. Polyimide asymmetric membrane with J(H2) up to 196 GPU and alpha(H2/TFE) higher than 1680 was developed for the separation. A pseudo-steady process was customized to sufficiently complete TFE recovery within the 30-min idle period after batch polymerization. With the procedure that H-2-enriched permeate is compressed back into the reactor, it is succeeded to overcome the limits that the purge is gradually falling in pressure and the TFE-enriched stream is hazardous in compression. In this instance, TFE recovery ratio was increased to about 90%. For a 5.0-kt/a TFE polymerization unit, the investment for the separation system is about 2.56 x 10(5) USD, the running payout is less than 4.35 x 10(4) USD/a, and meanwhile the annual gross profit can be up to 3.126 x 10(6) USD. On the whole, gas membrane separation is a promising technique to reduce TFE loss in the batch polymerization processes.
Tags
•
PFAS Universe
Data Source
Web of Science
2,2,2-Trifluoroethanol
Tetrafluoroethylene
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity