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HERO ID
7269603
Reference Type
Journal Article
Title
Crystal structure of β-d,l-fructose
Author(s)
Ishii, T; Senoo, T; Yoshihara, A; Fukada, K; Sakane, G; ,
Year
2015
Journal
Acta Crystallographica Section E-Crystallographic Communications
ISSN:
2056-9890
Language
English
PMID
26594441
DOI
10.1107/S2056989015016503
Abstract
The title compound, C6H12O6, was crystallized from an aqueous solution of equimolar mixture of d- and l-fructose (1,3,4,5,6-penta-hydroxy-hexan-2-one, arabino-hexulose or levu-lose), and it was confirmed that d-fructose (or l-fructose) formed β-pyran-ose with a (2) C 5 (or (5) C 2) conformation. In the crystal, two O-H⋯O hydrogen bonds between the hy-droxy groups at the C-1 and C-3 positions, and at the C-4 and C-5 positions connect homochiral mol-ecules into a column along the a axis. The columns are linked by other O-H⋯O hydrogen bonds between d- and l-fructose mol-ecules, forming a three-dimensional network.
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