US EPA

7324840 

Journal Article 

Direct and Selective Photocatalytic Oxidation of CH4 to Oxygenates with O2 on Cocatalysts/ZnO at Room Temperature in Water 

Song, H; Meng, X; Wang, S; Zhou, W; Wang, X; Kako, T; Ye, J 

2019 

Yes 

Journal of the American Chemical Society
ISSN: 0002-7863
EISSN: 1520-5126 

141 

51 

20507-20515 

English 

31834789 

10.1021/jacs.9b11440 

WOS:000505627300070 

Direct conversion of methane into methanol and other liquid oxygenates still confronts considerable challenges in activating the first C-H bond of methane and inhibiting overoxidation. Here, we report that ZnO loaded with appropriate cocatalysts (Pt, Pd, Au, or Ag) enables direct oxidation of methane to methanol and formaldehyde in water using only molecular oxygen as the oxidant under mild light irradiation at room temperature. Up to 250 micromoles of liquid oxygenates with ∼95% selectivity is achieved for 2 h over 10 mg of ZnO loaded with 0.1 wt % of Au. Experiments with isotopically labeled oxygen and water reveal that molecular O2, rather than water, is the source of oxygen for direct CH4 oxidation. We find that ZnO and cocatalyst could concertedly activate CH4 and O2 into methyl radical and mildly oxidative intermediate (hydroperoxyl radical) in water, which are two key precursor intermediates for generating oxygenated liquid products in direct CH4 oxidation. Our study underlines two equally significant aspects for realizing direct and selective photooxidation of CH4 to liquid oxygenates, i.e., efficient C-H bond activation of CH4 and controllable activation of O2.