Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
7429075
Reference Type
Journal Article
Title
Retention and selectivity properties of carbamate pesticides on novel polar-embedded stationary phases
Author(s)
Omamogho, JO; Stack, EM; Santalad, A; Srijaranai, S; Glennon, JD; Yamen, H; Albert, K; ,
Year
2010
Is Peer Reviewed?
Yes
Journal
Analytical and Bioanalytical Chemistry
ISSN:
1618-2642
EISSN:
1618-2650
Publisher
SPRINGER HEIDELBERG
Location
HEIDELBERG
Volume
397
Issue
6
Page Numbers
2513-2524
Language
English
PMID
20496174
DOI
10.1007/s00216-010-3816-3
Web of Science Id
WOS:000279453000053
URL
http://link.springer.com/10.1007/s00216-010-3816-3
Exit
Abstract
This study describes the use of stationary phases with polar functionality suitable for the chemical analysis of carbamates pesticides and comparing with conventional alkyl C8 and C18 phases. The emphasis of this study was to compare the selectivity and retention of the pesticides on different stationary phases, bonded onto 1.7 microm partially porous silica particles under isocratic separation condition. Four stationary phases including: phenylaminopropyl (PAP) phase, bidentate propylurea-C18 (BPUC(18)), C8 and C18, were successfully bonded on the partially porous silica spheres as evidenced by (29)Si and (13)C solid-state NMR analysis. The phenylaminopropyl phase exhibited smaller retentivity and enhanced selectivity compared to the alkyl C8 phase; the analysis time to run separation of the six carbamate pesticides (i.e., methomyl, propoxur, carbofuran, carbaryl, isoprocarb, and promecarb) on the PAP phase was threefold faster than alkyl C8 phase. In a similar manner, the BPUC(18) phase shows similar selectivity to that of the PAP phase, but with longer retentivity; although the BPUC(18) phase is characterized with a lesser degree of retentivity for the carbamate pesticides than the conventional alkyl C18 phase. We propose that pi-pi and weak polar interactions between the carbamate pesticides and the PAP phase dominates the separation mechanism and providing a superior selectivity; faster separation time was also achieved as a result of smaller retentivity. Whereas the C8 and C18 bonded phases exhibits only hydrophobic interactions with the pesticides, leading to larger retentivity. The BPUC(18) phase is shown to interact via polar-polar interactions in addition to hydrophobic interactions with the pesticides, providing similar selectivity with the PAP phase but with larger retentivity.
Keywords
Carbamate pesticides; Core-shell silica; Polar-embedded phase; Seeded growth mesoporous shell; Analysis time; Carbamate pesticides; Carbaryl; Carbofurans; Core-shell; Hydrophobic interactions; Isocratic separation; Methomyl; Polar interactions; Polar-embedded phase; Porous silica; Propoxur; Seeded growth; Separation mechanism; Solid state NMR; Stationary phasis; Agricultural chemicals; Alkylation; Hydrophobicity; Imaging techniques; Nuclear magnetic resonance spectroscopy; Pesticides; Shells (structures); Silica; Phase separation; carbamic acid derivative; carbon; isotope; pesticide; silicon; carbamic acid derivative; pesticide; article; hydrophobicity; liquid chromatography; methodology; nuclear magnetic resonance spectroscopy; chemical phenomena; liquid chromatography; procedures; Carbamates; Carbon Isotopes; Chromatography, Liquid; Hydrophobicity; Isotopes; Magnetic Resonance Spectroscopy; Pesticides; Silicon; Carbamates; Carbon Isotopes; Chromatography, Liquid; Hydrophobic and Hydrophilic Interactions; Isotopes; Magnetic Resonance Spectroscopy; Pesticides; Silicon
Conference Name
6th International Conference on Instrumental Methods of Analysis
Conference Location
Athens, GREECE
Tags
Other
•
Harmful Algal Blooms- Health Effects
April 2021 Literature Search
PubMed
WOS
Scopus
Saxitoxins
PubMed
WOS
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity