ENANTIOSELECTIVE SYNTHESIS OF (S)-1-METHYLDODECYL ACETATE, A PHEROMONE OF DROSOPHILA-MULLERI, VIA (-)-SPARTEINE-ASSISTED DEPROTONATION OF 1-DODECANOL | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7436029

Reference Type

Journal Article

Title

ENANTIOSELECTIVE SYNTHESIS OF (S)-1-METHYLDODECYL ACETATE, A PHEROMONE OF DROSOPHILA-MULLERI, VIA (-)-SPARTEINE-ASSISTED DEPROTONATION OF 1-DODECANOL

Author(s)

Hintze, F; Hoppe, D

Year

1992

Is Peer Reviewed?

Journal

Synthesis
ISSN: 0039-7881
EISSN: 1437-210X

Publisher

GEORG THIEME VERLAG

Location

STUTTGART

Issue

Page Numbers

1216-1218

Language

English

DOI

10.1055/s-1992-26340

Web of Science Id

WOS:A1992KD41000011

Abstract

The title compound was synthesized with 98% ee by enantioselective lithiation and methylation of 1-dodecanol, employing a new protection/activation method for primary alcohols, followed by asymmetric deprotonation of the carbamate.

Keywords

acetic acid 1 methyldodecyl ester; alkanol; pheromone; unclassified drug; article; enantiomer; reaction analysis; synthesis