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7450543 
Journal Article 
Selective Cleavage of Carbamate Protecting Groups from Aziridines with Otera's Catalyst 
Sun, S; Tirotta, I; Zia, N; Hutton, CA 
2014 
Yes 
Australian Journal of Chemistry
ISSN: 0004-9425
EISSN: 1445-0038 
CSIRO 
67 
3 
411-415 
English 
WOS:000332709400011 
Otera's distannoxane catalyst was found to promote the cleavage of carbamate groups from N-protected aziridines. This method enables the chemoselective cleavage of an aziridinyl N-carbobenzyloxy (Cbz) group in the presence of other N-Cbz groups. The selectivity is due to the longer, weaker N-C bond of aziridinyl carbamates, as inferred through IR and crystallographic analyses. © CSIRO 2014. 
Catalysts; Aziridines; Chemoselective; Crystallographic analysis; Distannoxane catalyst; Protecting group; Organic compounds 
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