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HERO ID
7492859
Reference Type
Journal Article
Title
Structure of binuclear adducts of Cu(II) carbamates and phosphates with bases from ESR data
Author(s)
Boguslavskii, EG; Shklyaev, AA
Year
1982
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Volume
31
Issue
6
Page Numbers
1159-1163
Language
English
DOI
10.1007/BF00955969
Abstract
1. For adducts of copper(II) carbamate and phosphate complexes in solutions a binuclear structure of the half-open lantern type is realized in which the two Cu2+ ions are connected only By two bridge anions present in the cis position relative to one another. The parameters of the ESR spectra for this low-symmetry structure have been assigned by modeling the spectra on a computer. 2. The rhombic component of the fine structure in the ESR spectra has been interpreted on the basis of a model of dipole-dipole interactions for nonpunctate magnetic dipoles. © 1982 Plenum Publishing Corporation.
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