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7501930 
Journal Article 
Electroorganic Chemistry. XX. Anodic Oxidation of Carbamates 
Shono, T; Hamaguchi, H; Matsumura, Y 
1975 
Yes 
Journal of the American Chemical Society
ISSN: 0002-7863
EISSN: 1520-5126 
97 
15 
4264-4268 
English 
The anodic oxidation of methyl N,N-dialkylcarbamate (4) in methanol yielded three types of products, that is, α-amethoxylated compound (5), enamine-type product (6) and dealkylated carbamate (7). Inter- and intramolecular isotope effects were measured to be 1.5-1.6 and 1.8-1.9, respectively. The reaction mechanism was discussed on the bases of product study, oxidation potential of carbamate, current-potential relationship, and isotope effect, and the electron transfer from the carbamate to anode was suggested as the initiation process. © 1975, American Chemical Society. All rights reserved. 
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