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7512700 
Journal Article 
Basic media behavior of N-[2-(1-hydroxy-2-Y-ethyl)phenyl] ethyl carbamates (Y = SMe, SOMe, SO2Me, H, Br, CN) 
Garcia Ruano, JL; Pedregal, C; Rodriguez, JH 
1989 
1 
Tetrahedron
ISSN: 0040-4020 
45 
1 
203-214 
English 
From the results obtained in the hydrolysis reaction of the carbamate group of some thioderivatives compounds whose common structure is (2 → tOOCNH-C6H4)-CHOH-CH2Y a mechanism is suggested to explain the products, as well as the relationship between the relative configuration of diastereoisomeric sulfoxides (Y = SOMe) with the reaction rate and with the stereochemical outcome. Other interesting and unexpected products are yielded when the hydrolysis reaction of others carbamates (Y = H, Br, CN) is carried out In the present cases, the carbamate functioh seems to behave as a very versatile group capable of readily undergoing conversions to several Kinds of heterocycles. © 1989. 
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