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7543879 
Journal Article 
Convenient preparation of alkyl benzyl imidodicarbonates, useful reagents for the direct synthesis of protected amines 
Grehn, L; Lurdes, M; Almeida, S; Ragnarsson, U 
1988 
1 
Synthesis
ISSN: 0039-7881
EISSN: 1437-210X 
Georg Thieme Verlag 
STUTTGART 
1988 
12 
992-994 
English 
WOS:A1988R288100023 
New mixed alkyl benzyl imidodicarbonates were prepared by reaction of benzyloxycarbonyl isocyanate with appropriate alcohols. This simple procedure also furnished alternative, more convenient routes to dibenzyl and benzyl 9-fluorenylmethyl imidodicarbonates. The substances are of interest as potential Gabriel reagents. Completely selective removal of one of the alkoxycarbonyl groups from the N-atom of the imidodicarbonates was demonstrated in several instances, giving benzyl carbamate or the alternative carbamate. © 1988 Georg Thieme Verlag. All rights reserved. 
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