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7547232 
Journal Article 
Carbon DioxideA Reagent for the Protection of Nucleophilic Centers and the Simultaneous Activation for Electrophilic Attack. Part 4.1 the α-Substitution of (i) Benzyl Alcohol and (II) Benzylamine 
Katritzky, AR; Fan, WQ; Akutagawa, K 
1987 
Synthesis
ISSN: 0039-7881
EISSN: 1437-210X 
Georg Thieme Verlag 
1987 
415-418 
English 
Benzyl alcohol is converted into a variety of α-substituted derivatives by a one-pot sequence involving lithiation of an intermediate hemicarbonate ester. Benzylamine is similarly converted by a one-pot sequence to α-substituted benzylamines: Here an intermediate carbamate salt is involved. © 1987 Georg Thieme Verlag. All rights reserved.