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Citation
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HERO ID
7555886
Reference Type
Journal Article
Title
Amination of meso-Bromoporphyrins and 9-Haloanthracenes with Diarylamines Catalyzed by a Palladium-PEPPSI Complex
Author(s)
Suzuki, Y; Fukui, N; Murakami, Kei; Yorimitsu, H; Osuka, A; ,
Year
2013
Publisher
WILEY-V C H VERLAG GMBH
Location
WEINHEIM
Page Numbers
1066-1071
DOI
10.1002/ajoc.201300162
Web of Science Id
WOS:000328218000010
URL
http://doi.wiley.com/10.1002/ajoc.201300162
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Abstract
Palladium-catalyzed aminations of bulky aryl halides such as meso-bromoporphyrins and 9-haloanthracenes with diarylamines provided efficient syntheses of meso-aminoporphyrins and 9-aminoanthracenes. Commercially available and air-stable Pd-PEPPSI complexes that have N-heterocyclic carbene (NHC) as ligands have the highest catalytic activities. The scope of diarylamines is wide enough to use diphenylamine, phenoxazine, phenothiazine, 9,10-dihydroacrydine, and carbazole.
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