Amination of meso-Bromoporphyrins and 9-Haloanthracenes with Diarylamines Catalyzed by a Palladium-PEPPSI Complex | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

7555886

Reference Type

Journal Article

Title

Amination of meso-Bromoporphyrins and 9-Haloanthracenes with Diarylamines Catalyzed by a Palladium-PEPPSI Complex

Author(s)

Suzuki, Y; Fukui, N; Murakami, Kei; Yorimitsu, H; Osuka, A; ,

Year

2013

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Page Numbers

1066-1071

DOI

10.1002/ajoc.201300162

Web of Science Id

WOS:000328218000010

URL

http://doi.wiley.com/10.1002/ajoc.201300162
Exit

Abstract

Palladium-catalyzed aminations of bulky aryl halides such as meso-bromoporphyrins and 9-haloanthracenes with diarylamines provided efficient syntheses of meso-aminoporphyrins and 9-aminoanthracenes. Commercially available and air-stable Pd-PEPPSI complexes that have N-heterocyclic carbene (NHC) as ligands have the highest catalytic activities. The scope of diarylamines is wide enough to use diphenylamine, phenoxazine, phenothiazine, 9,10-dihydroacrydine, and carbazole.