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7555886 
Journal Article 
Amination of meso-Bromoporphyrins and 9-Haloanthracenes with Diarylamines Catalyzed by a Palladium-PEPPSI Complex 
Suzuki, Y; Fukui, N; Murakami, Kei; Yorimitsu, H; Osuka, A; , 
2013 
WILEY-V C H VERLAG GMBH 
WEINHEIM 
1066-1071 
Palladium-catalyzed aminations of bulky aryl halides such as meso-bromoporphyrins and 9-haloanthracenes with diarylamines provided efficient syntheses of meso-aminoporphyrins and 9-aminoanthracenes. Commercially available and air-stable Pd-PEPPSI complexes that have N-heterocyclic carbene (NHC) as ligands have the highest catalytic activities. The scope of diarylamines is wide enough to use diphenylamine, phenoxazine, phenothiazine, 9,10-dihydroacrydine, and carbazole.