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7558730 
Journal Article 
Indoloquinones, part 7. Total synthesis of the potent lipid peroxidation inhibitor carbazoquinocin C by an intramolecular palladium-catalyzed oxidative coupling of an anilino-1,4-benzoquinone 
Knolker, HJ; Frohner, W; Reddy, KR; , 
2002 
Synthesis
ISSN: 0039-7881
EISSN: 1437-210X 
GEORG THIEME VERLAG KG 
STUTTGART 
557-564 
A highly efficient total synthesis of the potent lipid peroxidation inhibitor carbazoquinocin C is presented. The key-step is a palladium(II)-catalyzed oxidative cyclization of an anilino-1,4-benzoquinone to a carbazole-1,4-quinone which proceeds in up to 91% yield. Using this approach the natural product is obtained in four steps and 39% overall yield starting from aniline.