MECHANISM OF RUTHENIUM(III) CATALYSIS IN BROMAMINE-T OXIDATION OF PROPANALDEHYDE AND BUTANALDEHYDE IN ACIDIC MEDIA | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7584278

Reference Type

Journal Article

Title

MECHANISM OF RUTHENIUM(III) CATALYSIS IN BROMAMINE-T OXIDATION OF PROPANALDEHYDE AND BUTANALDEHYDE IN ACIDIC MEDIA

Author(s)

Singh, NB; Singh, AK

Year

1991

Is Peer Reviewed?

Yes

Journal

Journal of the Indian Chemical Society
ISSN: 0019-4522

Volume

Issue

Page Numbers

494-496

Web of Science Id

WOS:A1991HE09300004

URL

http://://WOS:A1991HE09300004
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Abstract

Kinetics of Ru(III) catalysed oxidation of propanaldehyde and butanaldehyde by acidic solution of bromamine-T have been investigated. The results show that oxidation of both the aldehydes follows first order kinetics in bromamine-T, both aldehydes, hydrogen ion concentration and Ru(III). Decreasing effect of [chloride ion] variation on reaction rate was observed. No effect of p-toluene sulphonamide and ionic strength of the medium was observed. Activation parameters have been evaluated. A suitable mechanism in confirmity with the results has been proposed.