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HERO ID
7585631
Reference Type
Journal Article
Title
Direct functionalization of alkyl ethers to construct hemiaminal ether skeletons (HESs)
Author(s)
Dian, LY; Xing, QY; Zhang-Negrerie, D; Du, YF
Year
2018
Is Peer Reviewed?
1
Journal
Organic and Biomolecular Chemistry
ISSN:
1477-0520
EISSN:
1477-0539
Volume
16
Issue
24
Page Numbers
4384-4398
DOI
10.1039/c8ob00793d
Web of Science Id
WOS:000436092600001
URL
http://
://WOS:000436092600001
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Abstract
Hemiaminal ether skeletons (HESs) are important backbones generally found in organic compounds. Compared to traditional functional group transformations, strategies for the C-H functionalization of alkyl ethers to construct HESs have drawn much attention in the past decade. In this review, we focus on the recent progress in developing various pathways to construct HESs via the direct functionalization of alkyl ethers, including: (a) the transition-metal-catalyzed nitrene insertion pathway, (b) the transition-metal-free organonitrenoid insertion pathway, (c) the transition-metal-catalyzed cross-coupling process and (d) the radical-involved cross-coupling pathway under metal-free conditions.
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