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Citation
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HERO ID
7597099
Reference Type
Journal Article
Title
Carbamates can cause corrosion problems
Author(s)
Dillon, CP
Year
1999
Is Peer Reviewed?
0
Journal
Materials Performance
ISSN:
0094-1492
Publisher
NACE
Location
Houston, TX, United States
Volume
38
Issue
12
Page Numbers
74-75
Language
English
Abstract
It is generally understood that the production of urea involves serious corrosion problems. The corrosive species in this reaction, in which the starting reagents are two moles anhydrous ammonia to one mole carbon dioxide, is not urea itself. It is the intermediate ammonium carbamate. The carbamate loses water to form urea. It should be noted that carbamic acid cannot exist itself, presumably decomposing into NH3 and CO2.
Keywords
Ammonia; Ammonium compounds; Carbon dioxide; Carboxylic acids; Urea; Ammonium carbamate; Corrosion
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