CONTRIBUTIONS TO THE CHEMISTRY OF THIOCOMPLEXES NEW COMPLEX-COMPOUNDS OF GOLD(III) WITH AROMATIC THIOAMIDES | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

7606275

Reference Type

Journal Article

Title

CONTRIBUTIONS TO THE CHEMISTRY OF THIOCOMPLEXES NEW COMPLEX-COMPOUNDS OF GOLD(III) WITH AROMATIC THIOAMIDES

Author(s)

Muresan, V; Muresan, N; Reiss, A; ,

Year

1993

Is Peer Reviewed?

Journal

Polish Journal of Chemistry
ISSN: 0137-5083

Publisher

POLISH CHEMICAL SOCIETY

Location

WARSAW

Page Numbers

2113-2119

Web of Science Id

WOS:A1993MJ91300003

Abstract

New complex compounds of Au(III) with thioamides of the phenylthioacetamide series and with thioamides of the dibenzofuran series are described. A correlation of elemental analysis, UV, visible, IR spectral analysis and conductivity measurements, suggests that the compounds are of [AuL2]Cl3 type (L=phenylthioacetamide, o-tolylthioacetamide, 2,5-dimethylthioacetamide) and [AuLCl2]Cl type (L=diphenyltioacetamide, 3-thioacetylamino-dibenzofuran, 3-thiobenzoylamino-dibenzofuran and 3-thiofuroylamino-dibenzofuran). The chemical bond implies the participation of both a sulphur atom and a nitrogen of the ''thione'' group in coordination to the metal. Electronic spectra show a plane-square geometry of the complexes.