Osmium(III) complexes with POP pincer ligands: preparation from commercially available OsCl(3)·3H(2)O and their X-ray structures | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

7606857

Reference Type

Journal Article

Title

Osmium(III) complexes with POP pincer ligands: preparation from commercially available OsCl(3)·3H(2)O and their X-ray structures

Author(s)

Asensio, G; Cuenca, AB; Esteruelas, MA; Medio-Simón, M; Oliván, M; Valencia, M; ,

Year

2010

Is Peer Reviewed?

Yes

Journal

Inorganic Chemistry
ISSN: 0020-1669
EISSN: 1520-510X

Publisher

AMER CHEMICAL SOC

Location

WASHINGTON

Page Numbers

8665-8667

Language

English

PMID

20828213

DOI

10.1021/ic101498h

Web of Science Id

WOS:000282084600007

URL

https://pubs.acs.org/doi/10.1021/ic101498h
Exit

Abstract

Complexes OsCl(3){dbf(P(i)Pr(2))(2)} [1; dbf(P(i)Pr(2))(2) = 4,6-bis(diisopropylphosphino)dibenzofuran], OsCl(3){xant(P(i)Pr(2))(2)} [2; xant(P(i)Pr(2))(2) = 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene], and OsCl(3){xant(PPh(2))(2)} [3; xant(PPh(2))(2) = 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene] have been obtained in high yield by the reaction of the corresponding diphosphine with OsCl(3)·3H(2)O. The ruthenium(III) counterparts RuCl(3){dbf(P(i)Pr(2))(2)} (4), RuCl(3){xant(P(i)Pr(2))(2)} (5), and RuCl(3){xant(PPh(2))(2)} (6) are similarly obtained from RuCl(3)·3H(2)O in moderate yields. The X-ray structures of dbf(P(i)Pr(2))(2) and complexes 1-3 are also reported.