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Citation
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HERO ID
7623183
Reference Type
Journal Article
Title
Diacetylene-Based C-2h-Symmetric Monomers for Two-Dimensional-Polymer Synthesis
Author(s)
Song, V; Ma, H; Ren, M; Ai, Z; Li, M; ,
Year
2017
Is Peer Reviewed?
1
Journal
Synlett
ISSN:
0936-5214
EISSN:
1437-2096
Publisher
GEORG THIEME VERLAG KG
Location
STUTTGART
Page Numbers
445-450
DOI
10.1055/s-0036-1588664
Web of Science Id
WOS:000402748600014
URL
http://www.thieme-connect.de/DOI/DOI?10.1055/s-0036-1588664
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Abstract
Two linear monomers with two terminal photoreactive groups (anthracene or maleimide) embedded in a diacetylene skeleton were synthesized for two-dimensional-polymer synthesis. Both of them were crystallized and their single-crystal structures were solved. It was found that the size of terminal groups can be critical for diacetylene's arrangement. The crystal structure of dimaleimide monomer revealed that maleimide groups strongly stacking in antiparallel and the photoinduced [2+2] cycloaddition of stacked maleimides was preliminary studied.
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