Flow-vacuum pyrolysis of polycyclic compounds. 19(1) - Pyrolysis of 11,12-dihydro-6H-dibenzo[a,e]cycloocten-5-OL | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7626742

Reference Type

Journal Article

Title

Flow-vacuum pyrolysis of polycyclic compounds. 19(1) - Pyrolysis of 11,12-dihydro-6H-dibenzo[a,e]cycloocten-5-OL

Author(s)

Parvulescu, L; Popescu, A; Banciu, A; Marton, G; Banciu, MD; ,

Year

2004

Is Peer Reviewed?

Journal

Revue Roumaine de Chimie
ISSN: 0035-3930

Publisher

EDITURA ACAD ROMANE

Location

BUCURESTI

Volume

Issue

Page Numbers

877-882

Language

English

Web of Science Id

WOS:000226821300010

Abstract

The flow-vacuum pyrolysis of the title alcohol 6, between 500degreesC and 850degreesC at 1.33 mbar in argon atmosphere, was investigated using GC/MS. The primary reaction products, 5,6-dihydro-dibenzo[a,e]cyclooctene (9) and 11,12-dihydro-6H-dibenzo[a, e]cycloocten-5-one (10) disappear at elevated temperatures where anthracene, 9-methylanthracene, 5H-10,11-dihydrodibenzo[a,d]cycloheptene (11) and 4b,5,9b,10-tetrahydroindeno[2,1a]indene (13) become the main reaction products. A radical mechanism explaining the formation of all above mentioned reaction products is suggested.