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HERO ID
7626952
Reference Type
Journal Article
Title
Diels-Alder reaction with anthracene and quinone derivatives on the dendritic periphery
Author(s)
Kim, C; Kim, H; Park, K; ,
Year
2004
Is Peer Reviewed?
Yes
Journal
Journal of Polymer Science. Part A, Polymer Chemistry
ISSN:
0887-624X
EISSN:
1099-0518
Publisher
WILEY
Location
HOBOKEN
Volume
42
Issue
9
Page Numbers
2155-2161
Language
English
DOI
10.1002/pola.20080
Web of Science Id
WOS:000220851800012
URL
http://doi.wiley.com/10.1002/pola.20080
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Abstract
Diels-Alder (DA) adducts including 24, 48, and 96 bicyclo end groups on the dendritic periphery were prepared by the reaction of anthracene on the dendrimers (first to fourth generation) and 1,4-benzoquinone as well as 1,4-naphtoquinone in boiled toluene. The structural information of DA adducts on the dendritic periphery was received from the hyperfine structural analysis by H-1 NMR spectroscopy. The gel permeation chromatography of DA products revealed very low polydispersity values and decreased regular retention time according to increasing generation. (C) 2004 Wiley Periodicals, Inc.
Keywords
Anthracene; Dendrimers; Diels-Alder polymers; Quinone; Silicones
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