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HERO ID
7636262
Reference Type
Journal Article
Title
Ruthenium(II) polyimine complexes with a long-lived 3IL excited state or a 3MLCT/3 IL equilibrium: efficient triplet sensitizers for low-power upconversion
Author(s)
Ji, S; Wu, W; Wu, W; Guo, H; Zhao, J; ,
Year
2011
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Publisher
WILEY-V C H VERLAG GMBH
Location
WEINHEIM
Volume
50
Issue
7
Page Numbers
1626-1629
Language
English
PMID
21308919
DOI
10.1002/anie.201006192
Web of Science Id
WOS:000287162900020
URL
http://doi.wiley.com/10.1002/anie.201006192
Exit
Abstract
Up, up, and away! The long-lived 3IL excited states of Ru II polyimine complexes were found to be more efficient in sensitizing upconversion based on triplet-triplet annihilation (TTA) and energy transfer (TTET) than the shorter-lived 3MLCT excited states (see picture). Upconversion occurs with an anti-Stokes shift of up to 0.77a eV. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
photochemistry; pyrene; ruthenium; triplet excited states; upconversion
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