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7638542 
Journal Article 
Amphoteric, Sulfonamide-Functionalized "Polysoaps": CO2-Induced Phase Separation for Water Remediation 
Pickett, PD; Kasprzak, CR; Siefker, DT; Abel, BA; Dearborn, MA; Mccormick, CL; , 
2018 
1 
Macromolecules
ISSN: 0024-9297
EISSN: 1520-5835 
AMER CHEMICAL SOC 
WASHINGTON 
51 
21 
9052-9059 
English 
WOS:000450694900074 
Amphoteric polysoaps have been prepared via statistical RAFT copolymerization using either methacryloyl sulfacetamide (mSAC) or methacryloyl sulfmethazine (mSMZ) and 4-hexylphenyl methylacrylamide (4HPhMA). These copolymers form pH- and CO2-responsive polymeric micelles capable of sequestering hydrophobic molecules in water. The composition and structure of the respective copolymers can be changed to tailor the onset and extent of CO2-dependent phase behavior. When CO2 is introduced into the system, resulting in carbonic acid formation, the pH drops below the pK(a) of the sulfonamide units along the copolymer backbone, and phase separation occurs. Purging with N-2 results in an increase in pH and redissolution of the polysoap; this process can be repeated multiple times. The mSMZ polysoaps, which show complete phase transitions using this reversible process, were especially efficient in removing the model contaminants pyrene and 9-anthracenemethanol from water. The feasibility of recovering and reusing these copolymers is demonstrated, pointing to the potential utility of such CO2-responsive systems in water treatment and related environmental remediation applications.