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HERO ID
7664432
Reference Type
Journal Article
Title
A new and convenient synthesis of 15H-16,17-dihydrocyclopenta[a]phenanthrene derivatives
Author(s)
Parihar, JA; Jaiswar, MM; Ramana, MMV; ,
Year
2005
Is Peer Reviewed?
1
Journal
Indian Journal of Chemistry. Section B
ISSN:
0376-4699
EISSN:
0975-0983
Publisher
NATL INST SCIENCE COMMUNICATION & INFORMATION RESOURCES-NISCAIR
Location
NEW DELHI
Volume
44
Issue
7
Page Numbers
1500-1504
Language
English
Web of Science Id
WOS:000230753500016
Abstract
Methyl 2-oxocyclopentane-l-carboxylate is selectively C-alkylated with several 2-(3,4-dihydro-l-naphthalenyl)ethyl-4-methylphenylsulphonates to give the corresponding seco-steroids, which on cyclodehydration followed by degradation in 5% Pd-C has afforded the corresponding title compounds.
Keywords
2-Oxocyclopentane-1-carboxylate; C-alkylation; Cyclopenta-phenanthrene derivatives; Methylphenylsulphonates; Pd-C; Seco-steroids
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