Alkoxy aluminum chlorides in the cationic polymerization of isobutylene: a co-initiator, carbocation stabilizer and chain-transfer agent | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

7695332

Reference Type

Journal Article

Title

Alkoxy aluminum chlorides in the cationic polymerization of isobutylene: a co-initiator, carbocation stabilizer and chain-transfer agent

Author(s)

Shiman, D; Vasilenko, IV; Kostjuk, S; ,

Year

2019

Is Peer Reviewed?

Journal

Polymer Chemistry
ISSN: 1759-9962
EISSN: 1759-9954

Publisher

ROYAL SOC CHEMISTRY

Location

CAMBRIDGE

Volume

Issue

Page Numbers

5998-6002

Language

English

DOI

10.1039/c9py01317b

Web of Science Id

WOS:000496531500006

URL

http://xlink.rsc.org/?DOI=C9PY01317B
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Abstract

Alkoxy aluminum chlorides are efficient catalysts for the preparation of well-defined exo-olefin terminated PIBs of low (M-n similar to 1000 g mol(-1)) to medium (M-n up to 50 000 g mol(-1)) molecular weight under mild experimental conditions (n-hexane as a solvent, [IB] = 5.8 M, temperature from -20 degrees C to 20 degrees C).