Electrochemical enol ether/olefin cross-metathesis in a lithium perchlorate/nitromethane electrolyte solution | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7698311

Reference Type

Journal Article

Title

Electrochemical enol ether/olefin cross-metathesis in a lithium perchlorate/nitromethane electrolyte solution

Author(s)

Miura, T; Kim, S; Kitano, Y; Tada, M; Chiba, K

Year

2006

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Volume

Issue

Page Numbers

1461-1463

Language

English

PMID

16440381

DOI

10.1002/anie.200503656

Web of Science Id

WOS:000235628700029

Abstract

(Chemical Equation Presented) Electrolytically generated four-membered-ring radical-cation intermediates are involved in the anodic olefin cross-metathesis of enol ethers and olefins in a lithium perchlorate/nitromethane electrolyte solution (see scheme). The reaction mechanism was investigated through deuterium-labeling studies. Â© 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

Alkenes; Electrochemistry; Enol ethers; Metathesis; Oxidation