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HERO ID
7698311
Reference Type
Journal Article
Title
Electrochemical enol ether/olefin cross-metathesis in a lithium perchlorate/nitromethane electrolyte solution
Author(s)
Miura, T; Kim, S; Kitano, Y; Tada, M; Chiba, K
Year
2006
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
45
Issue
9
Page Numbers
1461-1463
Language
English
PMID
16440381
DOI
10.1002/anie.200503656
Web of Science Id
WOS:000235628700029
Abstract
(Chemical Equation Presented) Electrolytically generated four-membered-ring radical-cation intermediates are involved in the anodic olefin cross-metathesis of enol ethers and olefins in a lithium perchlorate/nitromethane electrolyte solution (see scheme). The reaction mechanism was investigated through deuterium-labeling studies. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Keywords
Alkenes; Electrochemistry; Enol ethers; Metathesis; Oxidation
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