Free-Radical-Promoted Alkenylation of C(sp(3))-H Bond in Chloroalkane with Cinnamic Acid and beta-Nitrostyrene | Health & Environmental Research Online (HERO)

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HERO ID

7700750

Reference Type

Journal Article

Title

Free-Radical-Promoted Alkenylation of C(sp(3))-H Bond in Chloroalkane with Cinnamic Acid and beta-Nitrostyrene

Author(s)

Sun, M; Xu, Z; Li, W; Yang, Le; You, H; Yu, Dan; Fang, F; Wang, Y; Liu, ZQ; ,

Year

2020

Is Peer Reviewed?

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4150
EISSN: 1615-4169

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

362

Issue

Page Numbers

2195-2199

Language

English

DOI

10.1002/adsc.202000215

Web of Science Id

WOS:000522318600001

URL

https://onlinelibrary.wiley.com/doi/abs/10.1002/adsc.202000215
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Abstract

We demonstrated herein a free-radical alkenylation of the C(sp(3))-H bond in 1,2-dichloroethane with cinnamic acid and beta-nitrostyrene. This method not only provides a facile approach to chloroalkylated styrenes, but also would be instructive for halogen-atom directing selective functionalization of inert C(sp(3))-H bond.

Keywords

Cinnamic acid; CâH activation; Decarboxylation; Free-radical; Haloalkane