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7730454 
Journal Article 
Two Three-fold Interpenetrating Co/Cd Architectures Based on Right- and Left-helical Chains 
Zhou Man-Ling; Zhang Shi-Ting; Wu Yan-Bin; Liu Yang 
2020 
Yes 
Chinese Journal of Structural Chemistry
ISSN: 0254-5861 
Fujian Institute of Research of the Structure of Matter 
39 
8 
1483-1488 
English 
WOS:000560528700014 
Two Cd(II) and Co(II)-based complexes formulated as [Cd(bimh)(L)]·2H2O (1) and [Co(bimh)(L)]·2H2O (2) (bimh = 1,6-bis(imidazole-1-yl)hexane, H2L = 4,4΄-(methylenebis(oxy))dibenzoic acid) have been successfully prepared under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that the two complexes are isostructural and crystallize in Pbca space group. The whole three-dimensional (3D) architecture is based on three-fold interpenetrated layers containing double helical chains. In addition, the IR, TG and photoluminescence properties were also investigated. © 2020 Fujian Institute of Research of the Structure of Matter. All rights reserved. 
crystal structure; helical; interpenetrating; photoluminescence