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7734518 
Journal Article 
Surface-gel-conversion synthesis of submicron-thick MFI zeolite membranes to expedite shape-selective separation of hexane isomers 
Rong, H; Wang, G; Yan, J; Zou, X; Zhu, G 
2021 
Science in China Press 
64 
2 
374-382 
English 
WOS:000559948500001 
Ultrathin zeolite membranes are of paramount importance in accelerating gas transport during membrane separation, and lowering down their membrane thicknesses to submicron scale is deemed to be very challenging. Herein, we develop an advanced approach of surface gel conversion for synthesis of submicron-thick pure silica MFI (silicalite-1) zeolite membranes. Viscous gel is prepared by finely adjusting the precursor composition, enabling its reduced wettability. The unfavorable wetting of the support surface can effectively prevent gel penetration into alumina support voids. Aided by the seeds, the surface gel is directly and fully crystallized into an MFI zeolite membrane with minimal water steam. A membrane with a thickness of 500 nm is successfully acquired and it is free of visible cracks. Additionally, the as-synthesized membranes exhibit rapid and selective separation of hexane isomers by virtue of unprecedentedly high n-hexane permeance of 24.5×10−7 mol m−2 s−1 Pa−1 and impressive separation factors of 13.3-22.6 for n-hexane over its isomers. This developed approach is of practical interest for sustainable synthesis of high-quality zeolite membranes. © 2020, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature. 
zeolite synthesis; silica gel chemistry; thin membrane; hexane separation; isomer selectivity