Influence of mobile phase composition on the enantioseparation of methoxyl flavanones with self-prepared CDMPC column and chiral recognition mechanism | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7735653

Reference Type

Journal Article

Title

Influence of mobile phase composition on the enantioseparation of methoxyl flavanones with self-prepared CDMPC column and chiral recognition mechanism

Author(s)

Shao, BH; Xu, XZ; De Lu, J; Zou, L; Fu, XY

Year

2003

Is Peer Reviewed?

Journal

Chinese Chemical Letters
ISSN: 1001-8417
EISSN: 1878-5964

Publisher

CHINESE CHEMICAL SOCIETY

Location

BEIJING

Volume

Issue

Page Numbers

401-403

Language

English

Web of Science Id

WOS:000182738600022

Abstract

The influence of different alcohol modifiers in mobile phase on the chiral separation of 4â²-methoxyl flavanone, 5-methoxyl flavanone and 6-methoxyl flavanone on cellulose tris (3, 5-dimethylphenylcarbamate) (CDMPC) column was studied and the chiral recognition mechanism was discussed. Using hexane-tert-butanol (1.31 mol L-1) as the mobile phase, those three methoxyl flavanones were excellently separated on CDMPC chiral column.

Keywords

cellulose tris (3,5-dimethylphenylcarbamate); methoxyl flavanone; chiral stationary phase; enantioseparation