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HERO ID
7745523
Reference Type
Journal Article
Title
Preparation, surface-active and antielectrostatic properties of multiple quaternary ammonium salts
Author(s)
Wegrzynska, J; Chlebicki, Jan
Year
2006
Is Peer Reviewed?
Yes
Journal
Journal of Surfactants and Detergents
ISSN:
1097-3958
EISSN:
1558-9293
Publisher
WILEY
Location
HOBOKEN
Volume
9
Issue
3
Page Numbers
221-226
Language
English
DOI
10.1007/s11743-006-5000-5
Web of Science Id
WOS:000240609400002
Abstract
A series of new cationic surfactants, bis-quaternary ammonium salts and tris-ammonium salts, were prepared from N,N-dimethyldodecylamine and a product of the reaction of epichlorohydrin with ethyl-, propyl-, butyl-, pentyl-, hexyl-, and octylamine (in the case of bis-ammonium salts) or the hydrochloride of diethyl-, dipropyl-, dibutyl-, or dihexylamine (in the case of tris-ammonium salts). The obtained multiple salts were examined with respect to their surface-active properties: Critical micelle concentrations (CMC), effectiveness of surface tension reductions (γCMC), and adsorption efficiencies (pC 20) were measured. All these surfactants showed good water solubility and low CMC of more than one order of magnitude lower than those of corresponding monoalkylammonium salts. They also showed good foaming properties, but worse wetting capability. The obtained multiple salts showed excellent antielectrostatic properties. COPYRIGHT © 2006 BY AOCS PRESS.
Keywords
antielectrostatic effect; bis-quaternary ammonium salt; cationic surfactant; critical micelle concentration; surface-active property; tris-quaternary ammonium salt
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