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HERO ID
7747113
Reference Type
Journal Article
Title
Synthesis of samarium telluride thin films by successive ionic layer adsorption and reaction (SILAR) method for supercapacitor application
Author(s)
Kumbhar, VS; Lokhande, AC; Gaikwad, NS; Lokhande, CD
Year
2016
Is Peer Reviewed?
1
Journal
Materials Science in Semiconductor Processing
ISSN:
1369-8001
Publisher
Elsevier Ltd
Location
OXFORD
Volume
46
Page Numbers
29-34
Language
English
DOI
10.1016/j.mssp.2015.10.012
Web of Science Id
WOS:000371916800006
Abstract
The present paper deals with synthesis of samarium telluride (Sm2Te3) thin films using simple and low cost successive ionic layer adsorption and reaction (SILAR) method for supercapacitor application. The Sm2Te3 thin films are characterized by X-ray diffraction (XRD) for structural determination, energy dispersive analysis of X-ray (EDAX) for elemental composition, field emission scanning electron microscopy (FE-SEM) for surface morphological study and contact angle measurement for wettability study. The Sm2Te3 exhibits orthorhombic crystal structure with cloud like surface morphology. The film surface showed lyophilic behavior with contact angle of 5.7° for propylene carbonate (PC). Further, electrochemical measurements are carried out in LiClO4-PC electrolyte using cyclic voltammetry (CV), galvanostatic charge discharge and electrochemical impedance spectroscopy (EIS) techniques. The Sm2Te3 film showed maximum specific capacitance and energy density of 144 F g-1 and 10 W h kg-1 respectively. The EIS study showed negligible change in resistive parameters after 1000 electrochemical cycles. © 2016 Published by Elsevier Ltd.
Keywords
Samarium telluride; X-ray diffraction; Cyclic voltammetry; Specific capacitance; Electrochemical impedance spectroscopy
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